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In the event of a short circuit or a hit by an object that could penetrate the battery cells, most batteries will start to burn or explode. Batteries that remain stable under the above probable conditions are considered reliable for use in BESS. Many of the batteries currently available on the market do not pass this test and are therefore not suitable for use in battery storage systems.",{"type":21,"content":632},[633],{"text":634,"type":27},"However, in other batteries, unstable chemical and thermal cathode materials (e.g. NMC) can trigger exothermic chemical reactions within a cell. This exothermic reaction is caused by excessive heat generation due to overcharging, internal or external short circuits, contamination during production, high heat exposure or mechanical damage. The internal temperature of a cell rises when the release of thermal energy increases the reaction rate of the cell chemistry. When a certain temperature threshold is exceeded, the self-accelerating reaction becomes uncontrollable and leads to thermal runaway. This can cause the battery cell to catch fire or even explode. The situation is further exacerbated by the release of oxygen from the cathode material, making the fire extremely difficult to extinguish.",{"type":21,"content":636},[637],{"text":638,"type":27},"Unlike other batteries, LiFePO4 batteries never experience thermal runaway. This eliminates the risk of overheating and possible fires. With a stable temperature profile under extreme conditions, LFP batteries have stable thermal behavior (up to 300°C) and are not self-igniting (from overcharging). In NMC or NCA cells, on the other hand, a short circuit can generate a very high temperature of over 700°C, which can melt the separator and spread to other cells. This results in a fire that cannot be extinguished even underwater, as the oxygen needed for combustion is already contained in the battery material. This is why the LFP battery is the preferred choice for use in battery storage systems.",{"type":21,"content":640},[641],{"text":642,"type":27,"marks":643},"Durability & Cycle Life",[644],{"type":626},{"type":21,"content":646},[647],{"text":648,"type":27},"When battery cells are exposed to chemical, thermal and mechanical changes, their original capacity loses a little with each charge and discharge process (duty cycle). This simply means that it stores less and less energy over time. You may also know this from your mobile phone when after 2 years even the fully charged battery only lasts half a day.",{"type":21,"content":650},[651],{"text":652,"type":27},"Due to the slightly lower cell voltage of 3.2V, LFP cells have a slightly lower energy density compared to NMC cells. 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The battery \"remembers\" the energy demand and adapts over time to only deliver the amount of energy needed for previous discharge cycles, rather than the full original capacity.",{"type":21,"content":668},[669],{"text":670,"type":27},"Lithium iron phosphate batteries have a high power density compared to other LIBs. This allows the LFP battery to handle charge and discharge currents along with increased pulse load capacity. With higher currents, LFP cells can be charged quickly, but constant fast charging will shorten the life of this battery. This effect of fast charging occurs to a lesser extent with LFP cells. Through intelligent system design, cost-effective solutions for stationary applications can be created that find the perfect balance between charge and discharge rates, cycle stability and lifetime. 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